[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain

Manson JL, Baldwin AG, Scott B, Bendix J, Del Sesto RE, Goddard PA, Kohama Y, Tran HE, Ghannadzadeh S, Singleton J, Lancaster T, Möller JS, Blundell SJ, Pratt FL, Zapf VS, Kang J, Lee C, Whangbo M-H & Baines C
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Manson, J. L., Baldwin, A. G., Scott, B., Bendix, J., Del Sesto, R. E., Goddard, P. A., … Baines, C. (2012). [Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain. Inorganic Chemistry, 51(14), 7520-7528. https://doi.org/10.1021/ic300111k
https://www.dora.lib4ri.ch/psi/islandora/object/psi:47573

[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN4F2 octahedra that form chains with bridging HF2- ligands. In spite of significant distortion of the HF2- bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with JFHF = 4.86 K.

Details
Publication Type

Journal Article

Title

[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain

Author(s)

Manson, Jamie L.

Baldwin, Adora G.

Scott, Brian

Bendix, Jesper

Del Sesto, Rico E.

Goddard, Paul A.

Kohama, Yoshimitsu

Tran, Hope E.

Ghannadzadeh, Saman

Singleton, John

Lancaster, Tom

Möller, Johannes S.

Blundell, Stephen J.

Pratt, Francis L.

Zapf, Vivien S.

Kang, Jinhee

Lee, Changhoon

Whangbo, Myung-Hwan

Baines, Christopher (3501 Bulk-µSR)

Journal

Inorganic Chemistry

Volume

51

Issue

14

Start Page

7520

End Page

7528

Publication Year

2012

Peer Review

Yes

Facility

SmuS

Beamline

LTF

Collection

PSI Publications