Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)

Wäckerlin C, Iacovita C, Chylarecka D, Fesser P, Jung TA & Ballav N
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Wäckerlin, C., Iacovita, C., Chylarecka, D., Fesser, P., Jung, T. A., & Ballav, N. (2011). Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ). Chemical Communications, 47(32), 9146-9148. https://doi.org/10.1039/c1cc12519b
https://www.dora.lib4ri.ch/psi/islandora/object/psi:14163

Sublimation of alkali halides (NaCl and LiCl) onto a pre-assembled hydrogen-bonded layer of TCNQ on Au(111) resulted in the formation of 2D ionic layers via a direct charge-transfer reaction without involvement of the substrate. The presented approach allows for the fabrication of different ionic layers, decoupled from the substrate and offering new, potentially interesting properties.

Details
Publication Type

Journal Article

Title

Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)

Author(s)

Wäckerlin, Christian (6215 Molecular Nanoscience)

Iacovita, Cristian

Chylarecka, Dorota (6215 Molecular Nanoscience)

Fesser, Petra

Jung, Thomas A. (6215 Molecular Nanoscience)

Ballav, Nirmalya

Journal

Chemical Communications

Volume

47

Issue

32

Start Page

9146

End Page

9148

Publication Year

2011

Peer Review

Yes

Collection

PSI Publications
Open Access