Muon spin relaxation study of misfit-layered cobalt dioxide [Ca&lt;sub&gt;0.85&lt;/sub&gt;OH]&lt;sub&gt;1.16&lt;/sub&gt;&lt;sup&gt;RS&lt;/sup&gt; [CoO&lt;sub&gt;2&lt;/sub&gt;]

Månsson, Martin; Ikedo, Yutaka; Nozaki, Hiroshi; Sugiyama, Jun; Russo, Peter L.; Andreica, Daniel; Shizuya, Mitsuyuki; Isobe, Masaaki; Takayama-Muromachi, Eiji

doi:10.1016/j.ssc.2009.10.047

Muon spin relaxation study of misfit-layered cobalt dioxide [Ca_0.85OH]_1.16^RS [CoO₂]

Månsson M, Ikedo Y, Nozaki H, Sugiyama J, Russo PL, Andreica D, Shizuya M, Isobe M & Takayama-Muromachi E

Citation

Månsson, M., Ikedo, Y., Nozaki, H., Sugiyama, J., Russo, P. L., Andreica, D., … Takayama-Muromachi, E. (2010). Muon spin relaxation study of misfit-layered cobalt dioxide [Ca_0.85OH]_1.16^RS [CoO₂]. Solid State Communications, 150(7-8), 307-310. https://doi.org/10.1016/j.ssc.2009.10.047

Persistent URL https://www.dora.lib4ri.ch/psi/islandora/object/psi:15859

In order to clarify the nature of a possible magnetic phase transition at T_m = 13 K for the misfit layered cobalt dioxide with a double rocksalt (RS-) type block, [Ca_0.85OH]_1.16^RS[CoO₂], we have measured the muon spin rotation and relaxation (μ⁺SR) spectra in the temperature (T) range between 1.8 and 20 K. All μ⁺SR parameters, such as the dipolar interaction frequency (f_μOH) due to the formation of μ⁺-OH, its asymmetry (A_μOH) and relaxation rate (σ_μOH), are found to be independent of T both above and below T_m. This is a clear indication that the transition at T_m is not due to magnetic order but has a structural and/or electronic origin. In addition, we have been able to determine the muon stopping site for this misfit layered compound. It is found to be located within the CaOH blocking layers, where the muon and OH-group form a water-like Hμ⁺ O unit as indicated by a very slow oscillation in the zero-field relaxation spectrum.