Both synthetic polymers (membranes, coatings, packaging) and natural polymers (DNA, proteins) are subject to radical-initiated degradation. In order to mitigate the deterioration of the polymer properties, antioxidant strategies need to be devised. We studied the reactions of poly(α-methylstyrene sulfonate), a model compound for fuel cell membrane materials, with different degrees of polymerization with OH^• radicals as well as subsequent reactions. We observed the resulting OH^•-adducts to react with oxygen and eliminate H₂O, the relative likelihood of which is determined by pH and molecular weight. The resulting radical cations can be reduced back to the parent molecule by cerium(_III). This 'repair' reaction is also dependent on molecular weight likely because of intramolecular stabilization. The results from this study provide a starting point for the development of new hydrocarbon-based ionomer materials for fuel cells that are more resistant to radical induced degradation through the detoxification of intermediates via damage transfer and repair pathways. Furthermore, a more fundamental understanding of the mechanisms behind conventional antioxidants in medicine, such as ceria nanoparticles, is achieved.