The magnetic phase of lithium transition metal phosphates LiMPO&lt;sub&gt;4&lt;/sub&gt; (M=Mn, Co, Ni) detected by μ&lt;sup&gt;+&lt;/sup&gt;SR

Ofer, Oren; Sugiyama, Jun; Brewer, Jess H.; Månsson, Martin; Prša, Krunoslav; Ansaldo, Eduardo J.; Kobayashi, Genki; Kanno, Ryoji

doi:10.1016/j.phpro.2012.04.063

The magnetic phase of lithium transition metal phosphates LiMPO₄ (M=Mn, Co, Ni) detected by μ⁺SR

Ofer O, Sugiyama J, Brewer JH, Månsson M, Prša K, Ansaldo EJ, Kobayashi G & Kanno R

Citation

Ofer, O., Sugiyama, J., Brewer, J. H., Månsson, M., Prša, K., Ansaldo, E. J., … Kanno, R. (2012). The magnetic phase of lithium transition metal phosphates LiMPO₄ (M=Mn, Co, Ni) detected by μ⁺SR. In G. M. Luke & J. Sonier (Eds.), Physics Procedia: Vol. 30. International conference on muon spin rotation, relaxation and resonance, muSR (pp. 160-163). https://doi.org/10.1016/j.phpro.2012.04.063

Persistent URL https://www.dora.lib4ri.ch/psi/islandora/object/psi:62348

The magnetic properties of the olivine-type compounds LiMPO₄ (M = Mn, Co, Ni) are probed using muon spin rotation/relaxation (μSR). These materials pose an appealing magnetic structure and a high -potential technological interest as cathode materials for future rechargeable Li-ion batteries. The LiMPO₄ family of compounds consists of a corner-sharing MO₆ octahedra of high-spin M₂₊ ions manifesting an antiferromagnetic ground state below TN ≈ 30 K. Additionally, these compounds belong to a class of materials exhibiting properties between two-and three dimensional systems. A comparative study between the family members is presented.

Details

Publication Type

Proceedings Paper

Title

The magnetic phase of lithium transition metal phosphates LiMPO₄ (M=Mn, Co, Ni) detected by μ⁺SR

Author(s)

Ofer, Oren

Sugiyama, Jun

Brewer, Jess H.

Månsson, Martin (3302 Neutron Spectroscopy)

Prša, Krunoslav (0000 PSI)

Ansaldo, Eduardo J.