New magnetic frameworks of [(CuF2(H2O)2)x(pyz)]

Lanza A, Fiolka C, Fisch M, Casati N, Skoulatos M, Rüegg C, Krämer KW & Macchi P
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Lanza, A., Fiolka, C., Fisch, M., Casati, N., Skoulatos, M., Rüegg, C., … Macchi, P. (2014). New magnetic frameworks of [(CuF2(H2O)2)x(pyz)]. Chemical Communications, 50(93), 14504-14507. https://doi.org/10.1039/c4cc06696k
https://www.dora.lib4ri.ch/psi/islandora/object/psi:9470

Pressure-driven orbital reordering in the quantum magnet [CuF2(H2O)2(pyz)], (pyz = pyrazine), dramatically affects its magnetic exchange interactions. The crystal chemistry of this system is enriched with a new phase above 3 GPa, surprisingly concomitant with other polymorphs. Moreover, we discovered an unprecedented compound with a different stoichiometry, [(CuF2(H2O)2)2(pyz)], featuring magnetic bi-layers.

Details
Publication Type

Journal Article

Title

New magnetic frameworks of [(CuF2(H2O)2)x(pyz)]

Author(s)

Lanza, A. (6311 Material Science)

Fiolka, C.

Fisch, M. (0000 PSI)

Casati, N. (6311 Material Science)

Skoulatos, M. (3302 Neutron Spectroscopy)

Rüegg, C. (3300 Neutron Scattering)

Krämer, K.W.

Macchi, Piero

Journal

Chemical Communications

Volume

50

Issue

93

Start Page

14504

End Page

14507

Publication Year

2014

Peer Review

Yes

Facility

SLS

Beamline

MS-Powder

Funding (EC, SNSF)

European Commission: PSI-FELLOW - International Fellowship Program on Materials & Matter, Energy & Environment, Human Health & Life-Sciences, and Accelerator Technology (290605)

Swiss National Science Foundation: Chemical bonding and reactions in molecular crystals at high pressure (144534)

Swiss National Science Foundation: Dimensional and Anisotropy Control of Model Quantum Magnets (150257)

Collection

PSI Publications
Open Access

Additional Information

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