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Photoion mass-selected threshold photoelectron spectroscopy to detect reactive intermediates in catalysis: from instrumentation and examples to peculiarities and a database
Hemberger, P., Pan, Z., Wu, X., Zhang, Z., Kanayama, K., & Bodi, A. (2023). Photoion mass-selected threshold photoelectron spectroscopy to detect reactive intermediates in catalysis: from instrumentation and examples to peculiarities and a database. Journal of Physical Chemistry C, 127(34), 16751-16763. https://doi.org/10.1021/acs.jpcc.3c03120
Tuning the zeolite acidity enables selectivity control by suppressing ketene formation in lignin catalytic pyrolysis
Pan, Z., Puente-Urbina, A., Batool, S. R., Bodi, A., Wu, X., Zhang, Z., … Hemberger, P. (2023). Tuning the zeolite acidity enables selectivity control by suppressing ketene formation in lignin catalytic pyrolysis. Nature Communications, 14(1), 4512 (9 pp.). https://doi.org/10.1038/s41467-023-40179-z
A direct liquid sampling interface for photoelectron photoion coincidence spectroscopy
Wu, X., Pan, Z., Steglich, M., Ascher, P., Bodi, A., Bjelić, S., & Hemberger, P. (2023). A direct liquid sampling interface for photoelectron photoion coincidence spectroscopy. Review of Scientific Instruments, 94(3), 034103 (9 pp.). https://doi.org/10.1063/5.0136665
Elucidation of radical- and oxygenate-driven paths in zeolite-catalysed conversion of methanol and methyl chloride to hydrocarbons
Cesarini, A., Mitchell, S., Zichittella, G., Agrachev, M., Schmid, S. P., Jeschke, G., … Pérez-Ramírez, J. (2022). Elucidation of radical- and oxygenate-driven paths in zeolite-catalysed conversion of methanol and methyl chloride to hydrocarbons. Nature Catalysis, 5, 605-614. https://doi.org/10.1038/s41929-022-00808-0
Continuous pyrolysis microreactors: hot sources with little cooling? New insights utilizing cation velocity map imaging and threshold photoelectron spectroscopy
Hemberger, P., Wu, X., Pan, Z., & Bodi, A. (2022). Continuous pyrolysis microreactors: hot sources with little cooling? New insights utilizing cation velocity map imaging and threshold photoelectron spectroscopy. Journal of Physical Chemistry A, 126(14), 2196-2210. https://doi.org/10.1021/acs.jpca.2c00766
<em>Operando </em>PEPICO unveils the catalytic fast pyrolysis mechanism of the three methoxyphenol isomers
Pan, Z., Bodi, A., van Bokhoven, J. A., & Hemberger, P. (2022). Operando PEPICO unveils the catalytic fast pyrolysis mechanism of the three methoxyphenol isomers. Physical Chemistry Chemical Physics, 24(36), 21786-21793. https://doi.org/10.1039/d2cp02741k
On the absolute photoionization cross section and threshold photoelectron spectrum of two reactive ketenes in lignin valorization: fulvenone and 2-carbonyl cyclohexadienone
Pan, Z., Bodi, A., van Bokhoven, J. A., & Hemberger, P. (2022). On the absolute photoionization cross section and threshold photoelectron spectrum of two reactive ketenes in lignin valorization: fulvenone and 2-carbonyl cyclohexadienone. Physical Chemistry Chemical Physics, 24(6), 3655-3663. https://doi.org/10.1039/D1CP05206C
Isomer-dependent selectivities in the pyrolysis of anisaldehyde
Wu, X., Zhang, Z., Pan, Z., Bjelić, S., Bodi, A., & Hemberger, P. (2022). Isomer-dependent selectivities in the pyrolysis of anisaldehyde. Energy and Fuels, 36(13), 7200-7205. https://doi.org/10.1021/acs.energyfuels.2c01455
Ketenes in the induction of the methanol-to-olefins process
Wu, X., Zhang, Z., Pan, Z., Zhou, X., Bodi, A., & Hemberger, P. (2022). Ketenes in the induction of the methanol-to-olefins process. Angewandte Chemie International Edition, 61(41), e202207777 (6 pp.). https://doi.org/10.1002/anie.202207777
Unimolecular thermal decarbonylation of vanillin stifled by the bimolecular reactivity of methyl-loss intermediate
Wu, X., Pan, Z., Bjelić, S., Hemberger, P., & Bodi, A. (2022). Unimolecular thermal decarbonylation of vanillin stifled by the bimolecular reactivity of methyl-loss intermediate. Journal of Analytical and Applied Pyrolysis, 161, 105410 (12 pp.). https://doi.org/10.1016/j.jaap.2021.105410
Isomer-dependent catalytic pyrolysis mechanism of the lignin model compounds catechol, resorcinol and hydroquinone
Pan, Z., Puente-Urbina, A., Bodi, A., van Bokhoven, J. A., & Hemberger, P. (2021). Isomer-dependent catalytic pyrolysis mechanism of the lignin model compounds catechol, resorcinol and hydroquinone. Chemical Science, 12(9), 3161-3169. https://doi.org/10.1039/D1SC00654A
Direct evidence on the mechanism of methane conversion under non-oxidative conditions over iron-modified silica: the role of propargyl radicals Unveiled
Puente-Urbina, A., Pan, Z., Paunović, V., Šot, P., Hemberger, P., & van Bokhoven, J. A. (2021). Direct evidence on the mechanism of methane conversion under non-oxidative conditions over iron-modified silica: the role of propargyl radicals Unveiled. Angewandte Chemie International Edition, 60(45), 24002-24007. https://doi.org/10.1002/anie.202107553
On the threshold photoelectron spectrum of fulvenone, a reactive ketene derivative in lignin valorization
Hemberger, P., Pan, Z., Bodi, A., van Bokhoven, J. A., Ormond, T. K., Ellison, G. B., … Baraban, J. H. (2020). On the threshold photoelectron spectrum of fulvenone, a reactive ketene derivative in lignin valorization. ChemPhysChem, 21(19), 2217-2222. https://doi.org/10.1002/cphc.202000477