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Spatio‐chemical heterogeneity of defect‐engineered metal‐organic framework crystals revealed by full‐field tomographic X‐ray absorption spectroscopy
Ferreira Sanchez, D., Ihli, J., Zhang, D., Rohrbach, T., Zimmerman, P., Lee, J., … Ranocchiari, M. (2021). Spatio‐chemical heterogeneity of defect‐engineered metal‐organic framework crystals revealed by full‐field tomographic X‐ray absorption spectroscopy. Angewandte Chemie International Edition, 60(18), 10032-10039. https://doi.org/10.1002/anie.202013422
Paired copper monomers in zeolite omega: the active site for methane‐to‐methanol conversion
Knorpp, A. J., Pinar, A. B., Baerlocher, C., McCusker, L. B., Casati, N., Newton, M. A., … van Bokhoven, J. A. (2021). Paired copper monomers in zeolite omega: the active site for methane‐to‐methanol conversion. Angewandte Chemie International Edition, 60(11), 5854-5858. https://doi.org/10.1002/anie.202014030
Role of the ionic environment in enhancing the activity of reacting molecules in zeolite pores
Pfriem, N., Hintermeier, P. H., Eckstein, S., Kim, S., Liu, Q., Shi, H., … Lercher, J. A. (2021). Role of the ionic environment in enhancing the activity of reacting molecules in zeolite pores. Science, 372(6545), 952-957. https://doi.org/10.1126/science.abh3418
Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
Bauer, G., Ongari, D., Tiana, D., Gäumann, P., Rohrbach, T., Pareras, G., … Ranocchiari, M. (2020). Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation. Nature Communications, 11(1), 1059 (8 pp.). https://doi.org/10.1038/s41467-020-14828-6
The dynamics of overlayer formation on catalyst nanoparticles and strong metal-support interaction
Beck, A., Huang, X., Artiglia, L., Zabilskiy, M., Wang, X., Rzepka, P., … van Bokhoven, J. A. (2020). The dynamics of overlayer formation on catalyst nanoparticles and strong metal-support interaction. Nature Communications, 11(1), 3220 (8 pp.). https://doi.org/10.1038/s41467-020-17070-2
Discrimination of aluminum from silicon by electron crystallography with the Jungfrau detector
Fröjdh, E., Wennmacher, J. T. C., Rzepka, P., Mozzanica, A., Redford, S., Schmitt, B., … Gruene, T. (2020). Discrimination of aluminum from silicon by electron crystallography with the Jungfrau detector. Crystals, 10(12), 1-14. https://doi.org/10.3390/cryst10121148
Influence of water in the synthesis of the zirconium-based metal-organic framework UiO-66: isolation and reactivity of [ZrCl(OH)<sub>2</sub>(DMF)<sub>2</sub>]Cl
Taddei, M., Van Bokhoven, J. A., & Ranocchiari, M. (2020). Influence of water in the synthesis of the zirconium-based metal-organic framework UiO-66: isolation and reactivity of [ZrCl(OH)2(DMF)2]Cl. Inorganic Chemistry, 59(11), 7860-7868. https://doi.org/10.1021/acs.inorgchem.0c00991
Cu-erionite zeolite achieves high yield in direct oxidation of methane to methanol by isothermal chemical looping
Zhu, J., Sushkevich, V. L., Knorpp, A. J., Newton, M. A., Mizuno, S. C. M., Wakihara, T., … van Bokhoven, J. A. (2020). Cu-erionite zeolite achieves high yield in direct oxidation of methane to methanol by isothermal chemical looping. Chemistry of Materials, 32(4), 1448-1453. https://doi.org/10.1021/acs.chemmater.9b04223
Synthesis and characterization of alkenyl and alkyl substituted group 4 metallocene dichloride complexes: applications in ethylene polymerization
Ceballos-Torres, J., Gómez-Ruiz, S., Fajardo, M., Pinar, A. B., & Prashar, S. (2019). Synthesis and characterization of alkenyl and alkyl substituted group 4 metallocene dichloride complexes: applications in ethylene polymerization. Journal of Organometallic Chemistry, 899, 120890 (10 pp.). https://doi.org/10.1016/j.jorganchem.2019.120890
The influence of zeolite morphology on the conversion of methane to methanol on copper-exchanged omega zeolite (MAZ)
Knorpp, A. J., Newton, M. A., Sushkevich, V. L., Zimmermann, P. P., Pinar, A. B., & van Bokhoven, J. A. (2019). The influence of zeolite morphology on the conversion of methane to methanol on copper-exchanged omega zeolite (MAZ). Catalysis Science and Technology, 9(11), 2806-2811. https://doi.org/10.1039/c9cy00013e
Heavy atom labeling enables silanol defect visualization in silicalite-1 crystals
Li, T., Krumeich, F., Ihli, J., Ma, Z., Ishikawa, T., Pinar, A. B., & van Bokhoven, J. A. (2019). Heavy atom labeling enables silanol defect visualization in silicalite-1 crystals. Chemical Communications, 55(4), 482-485. https://doi.org/10.1039/c8cc07912a
The catalytic and radical mechanism for ethanol oxidation to acetic acid
Mostrou, S., Nagl, A., Ranocchiari, M., Föttinger, K., & van Bokhoven, J. A. (2019). The catalytic and radical mechanism for ethanol oxidation to acetic acid. Chemical Communications, 55(79), 11833-11836. https://doi.org/10.1039/C9CC05813C
Composites of copper nanowires in polyethylene: preparation and processing to materials with NIR dichroism
Nydegger, M., Deshmukh, R., Tervoort, E., Niederberger, M., & Caseri, W. (2019). Composites of copper nanowires in polyethylene: preparation and processing to materials with NIR dichroism. ACS Omega, 4(6), 11223-11228. https://doi.org/10.1021/acsomega.9b01077
Misconceptions and challenges in methane-to-methanol over transition-metal-exchanged zeolites
Ravi, M., Sushkevich, V. L., Knorpp, A. J., Newton, M. A., Palagin, D., Pinar, A. B., … van Bokhoven, J. A. (2019). Misconceptions and challenges in methane-to-methanol over transition-metal-exchanged zeolites. Nature Catalysis, 2(6), 485-494. https://doi.org/10.1038/s41929-019-0273-z
Increasing the activity of copper exchanged mordenite in the direct isothermal conversion of methane to methanol by Pt and Pd doping
Tomkins, P., Mansouri, A., Sushkevich, V. L., van der Wal, L. I., Bozbag, S. E., Krumeich, F., … van Bokhoven, J. A. (2019). Increasing the activity of copper exchanged mordenite in the direct isothermal conversion of methane to methanol by Pt and Pd doping. Chemical Science, 10(1), 167-171. https://doi.org/10.1039/C8SC02795A
Direct stepwise oxidation of methane to methanol over Cu-SiO<sub>2</sub>
Bozbag, S. E., Sot, P., Nachtegaal, M., Ranocchiari, M., van Bokhoven, J. A., & Mesters, C. (2018). Direct stepwise oxidation of methane to methanol over Cu-SiO2. ACS Catalysis, 8(7), 5721-5731. https://doi.org/10.1021/acscatal.8b01021
Characterization at the level of individual crystals: single-crystal MFI type zeolite grains
Gruene, T., Li, T., van Genderen, E., Pinar, A. B., & van Bokhoven, J. A. (2018). Characterization at the level of individual crystals: single-crystal MFI type zeolite grains. Chemistry: A European Journal, 24(10), 2384-2388. https://doi.org/10.1002/chem.201704213
Conversion of methane to methanol on copper mordenite: redox mechanism of isothermal and high-temperature-activation procedures
Knorpp, A. J., Newton, M. A., Pinar, A. B., & van Bokhoven, J. A. (2018). Conversion of methane to methanol on copper mordenite: redox mechanism of isothermal and high-temperature-activation procedures. Industrial and Engineering Chemistry Research, 57(36), 12036-12039. https://doi.org/10.1021/acs.iecr.8b01183
Copper-exchanged omega (MAZ) zeolite: copper-concentration dependent active sites and its unprecedented methane to methanol conversion
Knorpp, A. J., Pinar, A. B., Newton, M. A., Sushkevich, V. L., & van Bokhoven, J. A. (2018). Copper-exchanged omega (MAZ) zeolite: copper-concentration dependent active sites and its unprecedented methane to methanol conversion. ChemCatChem, 10(24), 5593-5596. https://doi.org/10.1002/cctc.201801809
Properties modification of nanosized hollow zeolite crystals by desilication
Li, T., Ma, Z., Krumeich, F., Knorpp, A. J., Pinar, A. B., & van Bokhoven, J. A. (2018). Properties modification of nanosized hollow zeolite crystals by desilication. ChemNanoMat, 4(9), 992-999. https://doi.org/10.1002/cnma.201800225