| Enhanced reducibility of the ceria-tin oxide solid solution modifies the CO oxidation mechanism at the platinum-oxide interface
Kopelent, R., Tereshchenko, A., Guda, A., Smolentsev, G., Artiglia, L., Sushkevich, V. L., … Safonova, O. V. (2021). Enhanced reducibility of the ceria-tin oxide solid solution modifies the CO oxidation mechanism at the platinum-oxide interface. ACS Catalysis, 11, 9435-9449. https://doi.org/10.1021/acscatal.1c01685 |
| Elucidating the oxygen activation mechanism on ceria-supported copper-oxo species using time-resolved X-ray absorption spectroscopy
Safonova, O. V., Guda, A., Rusalev, Y., Kopelent, R., Smolentsev, G., Teoh, W. Y., … Nachtegaal, M. (2020). Elucidating the oxygen activation mechanism on ceria-supported copper-oxo species using time-resolved X-ray absorption spectroscopy. ACS Catalysis, 10(8), 4692-4701. https://doi.org/10.1021/acscatal.0c00551 |
| Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays
Smolentsev, G., Milne, C. J., Guda, A., Haldrup, K., Szlachetko, J., Azzaroli, N., … Vogt, M. (2020). Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays. Nature Communications, 11, 2131 (9 pp.). https://doi.org/10.1038/s41467-020-15998-z |
| A DuMond-type crystal spectrometer for synchrotron-based X-ray emission studies in the energy range of 15–26 keV
Jagodziński, P., Szlachetko, J., Dousse, J. C., Hoszowska, J., Szlachetko, M., Vogelsang, U., … Nachtegaal, M. (2019). A DuMond-type crystal spectrometer for synchrotron-based X-ray emission studies in the energy range of 15–26 keV. Review of Scientific Instruments, 90(6), 063106 (12 pp.). https://doi.org/10.1063/1.5087948 |
| Fluorescence-detected XAS with sub-second time resolution reveals new details about the redox activity of Pt/CeO<sub>2</sub> catalyst
Guda, A. A., Bugaev, A. L., Kopelent, R., Braglia, L., Soldatov, A. V., Nachtegaal, M., … Smolentsev, G. (2018). Fluorescence-detected XAS with sub-second time resolution reveals new details about the redox activity of Pt/CeO2 catalyst. Journal of Synchrotron Radiation, 25(4), 989-997. https://doi.org/10.1107/S1600577518005325 |
| Pump-probe XAS investigation of the triplet state of an Ir photosensitizer with chromenopyridinone ligands
Smolentsev, G., van Vliet, K. M., Azzaroli, N., van Bokhoven, J. A., Brouwer, A. M., de Bruin, B., … Tromp, M. (2018). Pump-probe XAS investigation of the triplet state of an Ir photosensitizer with chromenopyridinone ligands. Photochemical and Photobiological Sciences, 17(7), 896-902. https://doi.org/10.1039/c8pp00065d |
| Structure of the Co<sup>I</sup> intermediate of a cobalt pentapyridyl catalyst for hydrogen evolution revealed by time-resolved X-ray spectroscopy
Smolentsev, G., Soldatov, M. A., Probst, B., Bachmann, C., Azzaroli, N., Alberto, R., … van Bokhoven, J. A. (2018). Structure of the CoI intermediate of a cobalt pentapyridyl catalyst for hydrogen evolution revealed by time-resolved X-ray spectroscopy. ChemSusChem, 11(18), 3087-3091. https://doi.org/10.1002/cssc.201801140 |
| Introducing time resolution to detect Ce<sup>3+</sup> catalytically active sites at the Pt/CeO<sub>2</sub> interface through ambient pressure X-ray photoelectron spectroscopy
Artiglia, L., Orlando, F., Roy, K., Kopelent, R., Safonova, O., Nachtegaal, M., … van Bokhoven, J. A. (2017). Introducing time resolution to detect Ce3+ catalytically active sites at the Pt/CeO2 interface through ambient pressure X-ray photoelectron spectroscopy. Journal of Physical Chemistry Letters, 8(1), 102-108. https://doi.org/10.1021/acs.jpclett.6b02314 |
| Low-temperature CO oxidation over combustion made Fe- and Cr-doped Co<sub>3</sub>O<sub>4</sub> catalysts: role of dopant's nature toward achieving superior catalytic activity and stability
Baidya, T., Murayama, T., Bera, P., Safonova, O. V., Steiger, P., Katiyar, N. K., … Haruta, M. (2017). Low-temperature CO oxidation over combustion made Fe- and Cr-doped Co3O4 catalysts: role of dopant's nature toward achieving superior catalytic activity and stability. Journal of Physical Chemistry C, 121(28), 15256-15265. https://doi.org/10.1021/acs.jpcc.7b04348 |
| Distribution of aluminum over different T-sites in ferrierite zeolites studied with aluminum valence to core X-ray emission spectroscopy
Bohinc, R., Hoszowska, J., Dousse, J. C., Błachucki, W., Zeeshan, F., Kayser, Y., … van Bokhoven, J. A. (2017). Distribution of aluminum over different T-sites in ferrierite zeolites studied with aluminum valence to core X-ray emission spectroscopy. Physical Chemistry Chemical Physics, 19(43), 29271-29277. https://doi.org/10.1039/c7cp05001a |
| Size-selective reactivity of subnanometer Ag<sub>4</sub> and Ag<sub>16</sub> clusters on a TiO<sub>2</sub> surface
Chen, P. T., Tyo, E. C., Hayashi, M., Pellin, M. J., Safonova, O., Nachtegaal, M., … Zapol, P. (2017). Size-selective reactivity of subnanometer Ag4 and Ag16 clusters on a TiO2 surface. Journal of Physical Chemistry C, 121(12), 6614-6625. https://doi.org/10.1021/acs.jpcc.6b11375 |
| Effect of ball milling on the electrocatalytic activity of Ba<sub>0.5</sub>Sr<sub>0.5</sub>Co<sub>0.8</sub>Fe<sub>0.2</sub>O<sub>3</sub> towards the oxygen evolution reaction
Cheng, X., Fabbri, E., Kim, B., Nachtegaal, M., & Schmidt, T. J. (2017). Effect of ball milling on the electrocatalytic activity of Ba0.5Sr0.5Co0.8Fe0.2O3 towards the oxygen evolution reaction. Journal of Materials Chemistry A, 5(25), 13130-13137. https://doi.org/10.1039/c7ta00794a |
| <em>Operando </em>X-ray absorption spectroscopy: a powerful tool toward water splitting catalyst development
Fabbri, E., Abbott, D. F., Nachtegaal, M., & Schmidt, T. J. (2017). Operando X-ray absorption spectroscopy: a powerful tool toward water splitting catalyst development. Current Opinion in Electrochemistry, 5(1), 20-26. https://doi.org/10.1016/j.coelec.2017.08.009 |
| Dynamic surface self-reconstruction is the key of highly active perovskite nano-electrocatalysts for water splitting
Fabbri, E., Nachtegaal, M., Binninger, T., Cheng, X., Kim, B. J., Durst, J., … Schmidt, T. J. (2017). Dynamic surface self-reconstruction is the key of highly active perovskite nano-electrocatalysts for water splitting. Nature Materials, 16(9), 925-931. https://doi.org/10.1038/nmat4938 |
| Effect of acid washing on the oxygen reduction reaction activity of Pt-Cu aerogel catalysts
Henning, S., Kühn, L., Herranz, J., Nachtegaal, M., Hübner, R., Werheid, M., … Schmidt, T. J. (2017). Effect of acid washing on the oxygen reduction reaction activity of Pt-Cu aerogel catalysts. Electrochimica Acta, 233, 210-217. https://doi.org/10.1016/j.electacta.2017.03.019 |
| Unraveling thermodynamics, stability, and oxygen evolution activity of strontium ruthenium perovskite oxide
Kim, B. J., Abbott, D. F., Cheng, X., Fabbri, E., Nachtegaal, M., Bozza, F., … Schmidt, T. J. (2017). Unraveling thermodynamics, stability, and oxygen evolution activity of strontium ruthenium perovskite oxide. ACS Catalysis, 7(5), 3245-3256. https://doi.org/10.1021/acscatal.6b03171 |
| Surface oxidation of supported Ni particles and its impact on the catalytic performance during dynamically operated methanation of CO<sub>2</sub>
Mutz, B., Gänzler, A. M., Nachtegaal, M., Müller, O., Frahm, R., Kleist, W., & Grunwaldt, J. D. (2017). Surface oxidation of supported Ni particles and its impact on the catalytic performance during dynamically operated methanation of CO2. Catalysts, 7(9), 279 (18 pp.). https://doi.org/10.3390/catal7090279 |
| From spectator species to active site using X-ray absorption and emission spectroscopy under realistic conditions
Nachtegaal, M., Hartfelder, U., & van Bokhoven, J. A. (2017). From spectator species to active site using X-ray absorption and emission spectroscopy under realistic conditions. In J. Frenken & I. Groot (Eds.), Springer series in chemical physics: Vol. 114. Operando research in heterogeneous catalysis (pp. 89-110). https://doi.org/10.1007/978-3-319-44439-0 |
| IrO<sub>2</sub>-TiO<sub>2</sub>: a high-surface-area, active, and stable electrocatalyst for the oxygen evolution reaction
Oakton, E., Lebedev, D., Povia, M., Abbott, D. F., Fabbri, E., Fedorov, A., … Schmidt, T. J. (2017). IrO2-TiO2: a high-surface-area, active, and stable electrocatalyst for the oxygen evolution reaction. ACS Catalysis, 7(4), 2346-2352. https://doi.org/10.1021/acscatal.6b03246 |
| Synthesis and properties of monolayer-protected Co<sub><em>x</em></sub>(SC<sub>2</sub>H<sub>4</sub>Ph)<sub><em>m</em></sub> nanoclusters
Pollitt, S., Pittenauer, E., Rameshan, C., Schachinger, T., Safonova, O. V., Truttmann, V., … Rupprechter, G. (2017). Synthesis and properties of monolayer-protected Cox(SC2H4Ph)m nanoclusters. Journal of Physical Chemistry C, 121(20), 10948-10956. https://doi.org/10.1021/acs.jpcc.6b12076 |
